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It is possible via Reporting.
Just search the Product Catalog -> Select all the records in result list-> Go to Tools -> Reporting -> Select the fields that you want in spreadsheet -> Export it to .csv file
You will get all data in Product Catalog in spraedsheet.
Just to add to HR's response, you'll need to search with the Advanced Search option.
1. Open the Product Catalogue
2. Under General Functions click Search Products
3. In the centre of the page in the Product Category section, click the Advanced Search button
Then when you perform a search you'll get the standard bulk function buttons like Select all, Report, etc.