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This should be easy enough. Looks like you have two different options here. You can set up a job that is linked with conditions to either the smart folder or all jobs at the end of the chain so that it runs after. This will be a web service type job that then makes your call. Alternatively you can have your smart folder order this web service job when it ends OK.
The second option is to have a shout to script action. The script then can perform your web call. Depending on if you want visibility into this action or not I would recommend utilizing Control-M jobs so that you can see the completion status of this web call alongside the completion status of all your other jobs.
To be clear, it is not possible to make a web call as a direct action and will require a job or script to be executed.